Addition of benzyltrimethylsilane to imines triggered by tetrabutylammonium fluoride
Author/Authors :
Zhang، نويسنده , , Wan-Xuan and Ding، نويسنده , , Chang-Hua and Luo، نويسنده , , Zhibin and Hou، نويسنده , , Xue-Long and Dai، نويسنده , , Li-Xin، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2006
Pages :
3
From page :
8391
To page :
8393
Abstract :
The addition of benzyltrimethylsilane 2 to imines 1 triggered by TBAF in the presence of 4A molecular sieves gave rise to the corresponding α-benzylated amines 3 in good yields. Moderate to high diastereoselectivity was obtained in the reactions of tert-butanesulfinyl imines with 2.
