Title of article
Chiral single-stranded metallohelix: metal-mediated folding of linear oligooxime ligand
Author/Authors
Akine، نويسنده , , Shigehisa and Taniguchi، نويسنده , , Takanori and Nabeshima، نويسنده , , Tatsuya، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
4
From page
8419
To page
8422
Abstract
A linear tetraoxime ligand H4L bearing chiral (S)-2-hydroxylpropyl groups at both ends was synthesized. Complexation between H4L with Zn2+ and Mn+ (=Ca2+, Y3+, La3+) afforded helical trinuclear complex [LZn2M]n+. The helical sense was the most effectively induced when Ca2+ was used as the central metal Mn+.
Keywords
Oxime , Salamo ligand , zinc complex , Helical structure , Chirality induction
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1853323
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