Author/Authors :
Levin، نويسنده , , Vitalij V. and Dilman، نويسنده , , Alexander D. and Belyakov، نويسنده , , Pavel A. and Struchkova، نويسنده , , Marina I. and Tartakovsky، نويسنده , , Vladimir A.، نويسنده ,
Abstract :
Nucleophilic addition of the pentafluorophenyl group from (C6F5)3SiF to non-activated imines affording α-C6F5-substituted secondary amines in high yield has been described. The reaction proceeds via simultaneous activation of imines and the silane reagent by means of a proton and chloride ion, respectively.
