Title of article
Cyclopropyl carbenoid insertion into alkenylzirconocenes—a convergent synthesis of alkenylcyclopropanes and alkylidenecyclopropanes
Author/Authors
Thomas، نويسنده , , Emma and Kasatkin، نويسنده , , Alexander N. and Whitby، نويسنده , , Richard J.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
5
From page
9181
To page
9185
Abstract
The insertion of cyclopropyl carbenoids into alkenylzirconocenes, derived by hydrozirconation of terminal alkynes, affords allylzirconium species which react with protons and isonitriles to afford alkenylcyclopropanes, and with aldehydes to afford alkylidene cyclopropanes. The addition of lithium carbenoid to zirconium occurs with the inversion of the organolithium centre.
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1853705
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