Title of article
A selective and convenient ruthenium mediated method for the synthesis of mixed acetals and orthoesters
Author/Authors
Krompiec، نويسنده , , Stanis?aw and Penczek، نويسنده , , Robert and Ku?nik، نويسنده , , Nikodem and Ma?ecki، نويسنده , , Jan Grzegorz and Matlengiewicz، نويسنده , , Marek، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
137
To page
140
Abstract
Addition of alcohols and phenols to O-allyl compounds (allyl ethers and acrolein acetals), catalyzed by [RuCl2(PPh3)3], was examined. Intramolecular addition of an OH group, leading to the formation of cyclic acetals and orthoesters, was also investigated. As a result, a new, selective and convenient method for the synthesis of symmetrical and unsymmetrical (mixed) acetals and orthoesters was developed.
Keywords
Mixed acetals , Addition , orthoesters , Ruthenium complexes , O-Allyl compounds
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1853860
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