Title of article
1,6-Remote stereocontrol using allylgermanes
Author/Authors
Thomas، نويسنده , , Eric J. and Weston، نويسنده , , Anna P.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
3
From page
341
To page
343
Abstract
Transmetallation of 5-hydroxy- and 5-methoxyhex-2-enyl(triethyl)germanes 8 and 9 with tin(IV) bromide is stereoselective and generates allyltin tribromides, which react with aldehydes to give (3Z)-homoallylic alcohols 3 with useful levels of 1,6-syn-stereocontrol.
Keywords
Remote stereocontrol , allylmetal , Organogermanium , diastereoselectivity
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1853926
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