Title of article :
1,6-Remote stereocontrol using allylgermanes
Author/Authors :
Thomas، نويسنده , , Eric J. and Weston، نويسنده , , Anna P.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2007
Abstract :
Transmetallation of 5-hydroxy- and 5-methoxyhex-2-enyl(triethyl)germanes 8 and 9 with tin(IV) bromide is stereoselective and generates allyltin tribromides, which react with aldehydes to give (3Z)-homoallylic alcohols 3 with useful levels of 1,6-syn-stereocontrol.
Keywords :
Remote stereocontrol , allylmetal , Organogermanium , diastereoselectivity
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
