Title of article
On the mechanism of stereoselection in direct Mannich reaction catalyzed by BINOL-derived phosphoric acids
Author/Authors
Gridnev، نويسنده , , Ilya D. and Kouchi، نويسنده , , Mitsuhiro and Sorimachi، نويسنده , , Keiichi and Terada، نويسنده , , Masahiro، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
497
To page
500
Abstract
Associates between the chiral phosphoric acids and Boc-protected imine were characterized computationally and by NMR; the primary importance of the bulky protecting group in imine for the high enantioselectivity in the direct Mannich reaction is rationalized via the analysis of the stereodiscriminating intermediates.
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1853980
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