Title of article
New amine-stabilized deuterated borane–tetrahydrofuran complex (BD3–THF): convenient reagent for deuterium incorporations
Author/Authors
Todd، نويسنده , , Robert C. and Hossain، نويسنده , , M. Mahmun and Josyula، نويسنده , , Kanth V. and Gao، نويسنده , , Peng and Kuo، نويسنده , , John and Tan، نويسنده , , C.T.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
3
From page
2335
To page
2337
Abstract
Convenient methods for the preparation of BD3–THF complex were developed. Certain amines stabilize the BD3–THF for long-term storage. Regioselectivity studies were carried out with the new amine-stabilized BD3–THF with representative olefins. Hydroboration of olefins provides a convenient tool for making corresponding deuterated alcohols after oxidation.
Keywords
Hydroboration , stability , olefins , regioselectivity , BD3–THF complex
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1854597
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