Title of article :
An expedient stereoselective synthesis of (Z)- and (E)-allyl iodides from Baylis–Hillman adducts along with selective iodination of benzylic alcohols using the polymethylhydrosiloxane–iodine system
Author/Authors :
Das، نويسنده , , Biswanath and Holla، نويسنده , , Harish and Srinivas، نويسنده , , Yallamalla and Chowdhury، نويسنده , , Nikhil and Bandgar، نويسنده , , B.P.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2007
Abstract :
A stereoselective method has been developed for the synthesis of (Z)- and (E)-allyl iodides from Baylis–Hillman adducts using polymethylhydrosiloxane (PMHS) and iodine in chloroform at room temperature. In addition, the reagent system has been utilized for the iodination of benzylic alcohols selectively.
Keywords :
Baylis–Hillman adduct , Polymethylhydrosiloxane (PMHS) , (Z)- and (E)-allyl iodides , iodine , Benzylic iodide
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
