Title of article
Phosphine triggered [3+2] allenoate–acrylate annulation: a mechanistic enlightenment
Author/Authors
Mercier، نويسنده , , Evan and Fonovic، نويسنده , , Branden and Henry، نويسنده , , Chris and Kwon، نويسنده , , Ohyun and Dudding، نويسنده , , Travis، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
3617
To page
3620
Abstract
A mechanistic study of phosphine-mediated [3+2] annulation of allenoate and acrylate is presented. The insight gained has identified that (1) [3+2] cycloaddition proceeds through a stepwise mechanism and (2) the involvement of a molecule of water, which services as a proton-shuttle, is essential for annulated product formation.
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1855001
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