Title of article
Ruthenium-catalyzed oxidative cyclization of 1,7-dienes. A novel diasteroselective synthesis of 2,7-disubstituted trans-oxepane diols
Author/Authors
Piccialli، نويسنده , , Vincenzo and Borbone، نويسنده , , Nicola and Oliviero، نويسنده , , Giorgia، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
5
From page
5131
To page
5135
Abstract
The ruthenium-catalyzed oxidation of some representative 1,7-dienes has been investigated. Tetrasubstituted 1,7-dienes are transformed into the corresponding trans-2,7-bis-hydroxyalkyl-oxepanes through an oxidative cyclization process. The process proceeds with an excellent stereoselectivity level.
Keywords
1 , trans-Oxepanes , 7-dienes , Ruthenium-catalyzed process , oxidative cyclization
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1855664
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