Title of article
Insertion reactions of macrocyclic rhodium carbenoids: a novel method for the synthesis of cryptands
Author/Authors
Muthusamy، نويسنده , , Sengodagounder and Gnanaprakasam، نويسنده , , Boopathy، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
6821
To page
6824
Abstract
Reaction of macrocyclic diazocarbonyl compounds and alcohols or diols in the presence of rhodium(II) acetate catalyst led to functionalized macrocyclic di- or tetralactones via O–H insertion. Interestingly, the double O–H insertion reaction with dihydroxy compounds gave cryptands of various ring sizes.
Keywords
carbenoids , Cryptands , diazo ketones , Macrocyclic lactones , Rhodium(II) acetate , O–H insertion
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1856580
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