Title of article
Total synthesis of aspinolide B: a ring-closing metathesis approach
Author/Authors
Ghosh، نويسنده , , Subhash and Rao، نويسنده , , R. Vengal and Shashidhar، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
6937
To page
6940
Abstract
A highly convergent stereoselective total synthesis of aspinolide B, a 10-membered lactone is described. The key step includes a ring-closing metathesis reaction to construct the 10-membered ring and the E—olefinic moiety. d-Mannitol was used as a chiral pool material for the construction of the key fragments—the olefinic acid and the olefinic alcohol moieties.
Keywords
ring-closing metathesis , d-Mannitol , Aspinolide B
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1856619
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