Title of article :
A simple and convenient method for the preparation of diborane from tetrabutylammonium borohydride and benzyl chloride for application in organic synthesis
Author/Authors :
Periasamy، نويسنده , , Mariappan and Muthukumaragopal، نويسنده , , G.P. and Sanjeevakumar، نويسنده , , Nalluri، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2007
Abstract :
Diborane is readily generated in situ at 25 °C in toluene using the Bu4NBH4/PhCH2Cl and Bu4NBH4/I2 reagent systems. The reagent prepared in this way is used for the reduction of carbonyl compounds and hydroboration–oxidation of olefins to obtain the corresponding alcohols in good yields.
Keywords :
Tetrabutylammonium borohydride , Hydroboration , Oxidation , Reduction
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
