Title of article
E/Z Isomerization of 3,3-disubstituted allylic thioethers
Author/Authors
Havranek، نويسنده , , Miroslav and Sauerberg، نويسنده , , Per and Kratina، نويسنده , , Pavel and Pihera، نويسنده , , Pavel، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
6970
To page
6973
Abstract
Allylic thioethers of the general structure 1 underwent E/Z isomerization during both basic and acidic hydrolysis of the ester moiety at the remote end of the molecule. The isomerization was dependent on the substitution of the allylic moiety. The presence of a 5-membered heterocycle on the double bond supported the isomerization. However, analogous oxy-ethers were stable.
Keywords
Allylic thioether , Allyl sulfide , E/Z isomerization
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1856632
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