Author/Authors :
Lyubimov، نويسنده , , Sergey E. and Tyutyunov، نويسنده , , Andrey A. and Kalinin، نويسنده , , Valery N. and Said-Galiev، نويسنده , , Ernest E. and Khokhlov، نويسنده , , Alexey R. and Petrovskii، نويسنده , , Pavel V. and Davankov، نويسنده , , Vadim A.، نويسنده ,
Abstract :
Novel monodentate phosphites containing ortho- and meta-closo-dodecarboranyl groups have been synthesized and applied in the asymmetric Rh-catalyzed hydrogenation of dimethyl itaconate, providing excellent enantioselectivities (up to 99.8% ee in CH2Cl2 and up to 93% ee in supercritical CO2).
Keywords :
asymmetric synthesis , Carboranes , Hydrogenation , Supercritical fluids , Rhodium
