Title of article
Relative carbanion basicities as driving force for an intramolecular silyl migration of lithiated biphenyls
Author/Authors
Bonnafoux، نويسنده , , Laurence and Scopelliti، نويسنده , , Rosario and Leroux، نويسنده , , Frédéric R. and Colobert، نويسنده , , Françoise، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
5
From page
8768
To page
8772
Abstract
A solvent-dependent silyl migration of lithiated biphenyls is described, involving the intermediate formation of a pentacoordinated silicate complex. Differences in the relative basicities of the aryllithium intermediates are the possible driving force for this migration.
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1857491
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