Title of article :
Anionic WS-TEMPO-mediatory electrooxidation of alcohols in water: halide-free oxidation directed towards a totally closed system
Author/Authors :
Mitsudo، نويسنده , , Koichi and Kumagai، نويسنده , , Hiroki and Takabatake، نويسنده , , Fumiko and Kubota، نويسنده , , Jun and Tanaka، نويسنده , , Hideo، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2007
Abstract :
Electrooxidation of alcohols in water with water-soluble N-oxyl derivatives bearing a sulfonic acid group (anionic WS-TEMPOs) as a mediator proceeded to afford the corresponding ketones and aldehydes in moderate to good yields. The aqueous solution containing WS-TEMPOs could be readily recovered and reused for the electrooxidation of alcohols, thereby providing a totally closed system.
Keywords :
Electrooxidation , Water-soluble mediator , N-Oxyl , TEMPO , alcohol , water
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
