Title of article
A facile and efficient stereoselective synthesis of highly functionalised trisubstituted alkene derivatives of ferrocenealdehyde
Author/Authors
Shanmugam، نويسنده , , Ponnusamy and Vaithiyanathan، نويسنده , , Vadivel and Viswambharan، نويسنده , , Baby and Madhavan، نويسنده , , Suchithra، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
5
From page
9190
To page
9194
Abstract
The reaction of the Baylis–Hillman adduct 2 of ferrocenealdehyde with various oxygen and carbon nucleophiles in the presence of montmorillonite K10 clay catalyst furnished highly functionalised trisubstituted alkene derivatives of ferrocenealdehyde in excellent yield. Synthetic use of one of products 7 has been demonstrated with the synthesis of a 1,3-diyne ether derivative of ferrocene 16 via an Eglinton coupling reaction.
Keywords
3-Diyne ether , Ferrocenealdehyde , Trisubstituted alkene , Baylis–Hillman adduct , 1 , Montmorillonite K10
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1857616
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