Title of article
Building carbohydrates on the dioxanone scaffold: stereoselective synthesis of d-glycero-d-manno-2-octulose
Author/Authors
Nagarjuna Palyam، نويسنده , , Nagarjuna and Niewczas، نويسنده , , Izabella and Majewski، نويسنده , , Marek، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
9195
To page
9198
Abstract
The title compound has been synthesized via two proline-catalyzed aldol addition reactions of 2,2-dialkyl-1,3-dioxan-5-ones: the first addition to 1,3-dithiane-2-carboxaldehyde, followed by reduction to the corresponding diol, protection of the OH groups and dithiane hydrolysis afforded a protected d-ribose that was used in the second aldol addition reaction.
Keywords
Higher sugars , proline , Dioxanone , Stereoselective aldol reaction , organocatalysis
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1857617
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