Title of article
Efficient catalysts for telomerization of butadiene with amines
Author/Authors
Anne Grotevendt، نويسنده , , Anne and Bartolome، نويسنده , , Maribel and Nielsen، نويسنده , , David J. and Spannenberg، نويسنده , , Anke and Jackstell، نويسنده , , Ralf and Cavell، نويسنده , , Kingsley J. and Oro، نويسنده , , Luis A. and Beller، نويسنده , , Matthias، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
5
From page
9203
To page
9207
Abstract
In situ-generated N-heterocyclic carbene (NHC) palladium catalysts and isolated NHC-palladium complexes have been tested for the telomerization reaction of 1,3-butadiene with primary and secondary amines. Superior catalyst activity (TON up to 400.000) and selectivity are obtained. Applying optimized conditions a variety of octa-2,7-dienylamines were prepared in high yield and excellent selectivity.
Keywords
3-Butadiene , 1 , PALLADIUM , Homogeneous catalysis , Carbene , Amines
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1857619
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