Title of article :
Scandium–bipyridine-catalyzed, enantioselective selenol addition to aromatic meso-epoxides
Author/Authors :
Tschِp، نويسنده , , Andreas and Nandakumar، نويسنده , , Mecheril Valsan and Pavlyuk، نويسنده , , Oksana and Schneider، نويسنده , , Christoph، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2008
Abstract :
A chiral scandium–bipyridine complex catalyzes the highly enantioselective addition of phenylselenol to aromatic meso-epoxides and furnishes 1,2-seleno alcohols in good yields and up to 94% ee. In addition, a sequential, one-pot epoxide opening-reduction protocol has been developed for the direct synthesis of 1,2-diaryl carbinols.
Keywords :
1 , scandium , epoxides , Catalysis , 2-Seleno alcohol , bipyridine
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
