Title of article
Osmium-catalyzed asymmetric dihydroxylation by carbon dioxide-activated hydrogen peroxide and N-methylmorpholine
Author/Authors
Balagam Bharathi، نويسنده , , Bharathi and Mitra، نويسنده , , Ranjan and Richardson، نويسنده , , David E.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
5
From page
1071
To page
1075
Abstract
An improved process has been developed for the osmium-catalyzed dihydroxylation of olefins via in situ formation of NMO from NMM using CO2 catalysis and H2O2. All olefins examined were selectively cis-dihydroxylated to their corresponding diols in good to excellent yields, and by the use of chiral ligands, high enantiomeric excesses were obtained.
Keywords
Peroxide , dihydroxylation , Catalysis , Peroxymonocarbonate , Carbon dioxide , Amine oxides , Asymmetric dihydroxylation
Journal title
Tetrahedron Letters
Serial Year
2008
Journal title
Tetrahedron Letters
Record number
1858168
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