Author/Authors :
Roy، نويسنده , , Brindaban and Pérez-Luna، نويسنده , , Alejandro and Ferreira، نويسنده , , Franck and Botuha، نويسنده , , Candice and Chemla، نويسنده , , Fabrice، نويسنده ,
Abstract :
A new addition reaction of a 3-alkoxy allenylzinc reagent to N-acyliminiums prepared in situ from imines and acid halides is reported. Unlike addition onto imines or nitrones that affords the trans adducts, acetylenic syn-1,2 amino ethers are yielded with good selectivities, thus providing a new entry to propargyl syn-1,2-aminoalcohol units.
