Title of article
Rhodium-catalyzed alkylthio exchange reaction of thioester and disulfide
Author/Authors
Arisawa، نويسنده , , Mieko and Kubota، نويسنده , , Tomohiro and Yamaguchi، نويسنده , , Masahiko، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
4
From page
1975
To page
1978
Abstract
The Wilkinson complex RhCl(PPh3)3 catalyzes equilibrating alkylthio exchange reaction of thioesters with disulfides. The treatment of a thioester and a dialkyl disulfide in refluxing diethyl ketone in the presence of RhCl(PPh3)3 (2.5 mol %) for 1.5 h gave an alkylthio exchanged thioester. The reaction of S-methyl ester was conducted shifting the equilibrium by removing volatile dimethyl disulfide.
Journal title
Tetrahedron Letters
Serial Year
2008
Journal title
Tetrahedron Letters
Record number
1858618
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