Title of article
Generation of rhodium enolates via retro-aldol reaction and its application to regioselective aldol reaction
Author/Authors
Murakami، نويسنده , , Kei and Ohmiya، نويسنده , , Hirohisa and Yorimitsu، نويسنده , , Hideki and Oshima، نويسنده , , Koichiro، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
3
From page
2388
To page
2390
Abstract
Retro-aldol reactions of β-hydroxy ketones take place under rhodium catalysis, leading to regioselective formation of the corresponding rhodium enolates. The enolates react with aldehydes in situ to afford the corresponding aldol adducts in high yields.
Keywords
aldol reaction , Rhodium , carbon–carbon bond cleavage , Retro-aldol reaction
Journal title
Tetrahedron Letters
Serial Year
2008
Journal title
Tetrahedron Letters
Record number
1858837
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