Title of article
Regioselective synthesis of trifluoromethyl group substituted allylic amines via palladium-catalyzed allylic amination
Author/Authors
Kawatsura، نويسنده , , Motoi and Hirakawa، نويسنده , , Takuya and Tanaka، نويسنده , , Tomoko and Ikeda، نويسنده , , Daiji and Hayase، نويسنده , , Shuichi and Itoh، نويسنده , , Toshiyuki، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
4
From page
2450
To page
2453
Abstract
The palladium-catalyzed regioselective allylic amination of α-trifluoromethylated allyl acetate occurred using Pd(OAc)2/DPPE and [Pd(π-allyl)(cod)]BF4/DPPF. The selective formation of the γ-product was attained by Pd(OAc)2/DPPE, while the α-product was obtained using [Pd(π-allyl)(cod)]BF4/DPPF.
Keywords
Allylic amination , PALLADIUM , fluorine , regioselectivity
Journal title
Tetrahedron Letters
Serial Year
2008
Journal title
Tetrahedron Letters
Record number
1858866
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