Title of article
Anionic σ-complexes of 1,3,5-tris(fluorosulfonyl)benzene
Author/Authors
Boiko، نويسنده , , Vladimir N. and Kamoshenkova، نويسنده , , Oksana M. and Filatov، نويسنده , , Andrey A.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
3
From page
2719
To page
2721
Abstract
We have found that symmetrical benzene trisulfonic-acid trifluoride 1 is able to undergo nucleophilic addition at free positions on the aromatic ring. Its reactions with sodium sulfite, morpholine and carbanions of malonic and acetoacetic esters, dimedone and nitromethane lead to the formation of comparatively stable anionic σ-complexes 3–8.
Keywords
3 , 1 , 5-Tris(fluorosulfonyl)benzene , Anionic ?-complexes , Aromatic sulfonic-acid fluorides , Aromatic nucleophilic addition
Journal title
Tetrahedron Letters
Serial Year
2008
Journal title
Tetrahedron Letters
Record number
1858989
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