Title of article
Novel oxidative nitrogen to carbon rearrangement found in the conversion of anilines to benzaldoximes by treating with HCHO/H2O2
Author/Authors
Kapuriya، نويسنده , , Naval and Kapuriya، نويسنده , , Kalpana and Dodia، نويسنده , , Narsinh M. and Lin، نويسنده , , Yi-Wen and Kakadiya، نويسنده , , Rajesh and Wu، نويسنده , , Chao-Ting and Chen، نويسنده , , Ching-Huang and Naliapara، نويسنده , , Yogesh and Su، نويسنده , , Tsann-Long، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
5
From page
2886
To page
2890
Abstract
Novel rearrangement was found by reacting anilines with HCHO/H2O2 resulting in the synthesis of various benzaldoximes. The mechanism of the rearrangement is proposed and suggested that the rearrangement might proceed via unstable N-phenyloxazirane intermediate followed by the transfer of aryl moiety from nitrogen to carbon atom leading to the formation of benzaldoxime.
Keywords
Rearrangement , Amines , Peroxides , Benzaldoximes , Oxidation
Journal title
Tetrahedron Letters
Serial Year
2008
Journal title
Tetrahedron Letters
Record number
1859071
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