Title of article :
A cross-metathesis approach to the stereocontrolled synthesis of the AB ring segment of ciguatoxin
Author/Authors :
Kadota، نويسنده , , Isao and Abe، نويسنده , , Takashi and Uni، نويسنده , , Miyuki and Takamura، نويسنده , , Hiroyoshi and Yamamoto، نويسنده , , Yoshinori، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2008
Abstract :
Synthesis of the AB ring segments of ciguatoxin is described. The present synthesis includes a Lewis acid mediated cyclization of allylstannane with aldehyde, cross-metathesis reaction introducing the side chain, and Grieco–Nishizawa dehydration on the A ring.
Keywords :
ciguatoxin , polycyclic ethers , Allylstannane–aldehyde condensation , cross-metathesis
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
