• Title of article

    Bi(OTf)3-catalyzed 5-exo-trig cyclization via halide activation

  • Author/Authors

    Hayashi، نويسنده , , Ryuji and Cook، نويسنده , , Gregory R.، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2008
  • Pages
    3
  • From page
    3888
  • To page
    3890
  • Abstract
    Lewis acid activation of allyl halides utilizing Bi(OTf)3 resulted in cationic cyclization of alkenes with high efficiency. While other Lewis acids could catalyze this process with highly substituted alkenes, bismuth salts demonstrated unique reactivity in come cases. This suggested that bismuth triflate possesses interesting halophilic properties.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2008
  • Journal title
    Tetrahedron Letters
  • Record number

    1859514