Title of article :
Oxidant-controlled regioselectivity in the oxidative arylation of N-acetylindoles
Author/Authors :
Shathaverdhan Potavathri، نويسنده , , Shathaverdhan and Dumas، نويسنده , , Ashley S. and Dwight، نويسنده , , Timothy A. and Naumiec، نويسنده , , Gregory R. and Hammann، نويسنده , , Jeffrey M. and DeBoef، نويسنده , , Brenton، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2008
Pages :
4
From page :
4050
To page :
4053
Abstract :
N-Acetylindoles can be oxidatively coupled with arenes such as benzene or pentafluorobenzene in dioxane. The use of Cu(OAc)2 as the stoichiometric oxidant produces selective arylation at the 3-position of indole while AgOAc produces selective arylation at indole’s 2-position.
Keywords :
regioselective , arylation , C–H functionalization , indole , oxidative coupling , PALLADIUM
Journal title :
Tetrahedron Letters
Serial Year :
2008
Journal title :
Tetrahedron Letters
Record number :
1859585
Link To Document :
https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1859585
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