Author/Authors :
Matsugi، نويسنده , , Masato and Hasegawa، نويسنده , , Masakazu and Hasebe، نويسنده , , Shohei and Takai، نويسنده , , Shohei and Suyama، نويسنده , , Ryusuke and Wakita، نويسنده , , Yusuke and Kudo، نويسنده , , Kanako and Imamura، نويسنده , , Hiromi and Hayashi، نويسنده , , Toshiya and Haga، نويسنده , , Seiichi، نويسنده ,
Abstract :
A simple procedure for the perfluoroalkylation of the aromatic ring of phenols under mildly basic conditions is described. Treatment of a variety of phenols with perfluoroalkyl iodide in the presence of the radical initiator V-70L and Cs2CO3 provided the corresponding perfluoroalkylated products in moderate to good yields. Generally, the reaction proceeded smoothly at room temperature to yield regioselectively perfluoroalkylated products.
