Author/Authors :
Rogachev، نويسنده , , Victor O. and Merten، نويسنده , , Sandra and Seiser، نويسنده , , Tobias and Kataeva، نويسنده , , Olga and Metz، نويسنده , , Peter، نويسنده ,
Abstract :
Alkylation of γ- and δ-sultams with (iodomethyl)trimethylsilane followed by treatment of the resultant silanes with tetrabutylammonium fluoride gave rise to sulfur-free unsaturated amines. In particular, N-THP substituted sultams were found to be useful substrates for the alkylation event. A corresponding one-pot transformation involving sultam α-alkylation with (iodomethyl)magnesium chloride is also reported.
Keywords :
Alkenylation , Alkylation , Desulfurization , sultams
