Title of article :
Radical chain reactions using THP as a solvent
Author/Authors :
Yasuda، نويسنده , , Hiroshi and Uenoyama، نويسنده , , Yoshitaka and Nobuta، نويسنده , , Osamu and Kobayashi، نويسنده , , Shoji and Ryu، نويسنده , , Ilhyong، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2008
Abstract :
THP (tetrahydropyran) has been found to show an excellent stability towards autooxidation, compared with THF. Tributyltin hydride mediated radical cyclization, when conducted in THF as a solvent, suffers from competition of hydrogen abstraction from the solvent, whereas the use of THP resulted in the course to negligible degree. Tributyltin hydride, TTMSS, and hexanethiol mediated radical reactions were carried out successfully using THP as a solvent.
Keywords :
Radical reaction , THP , Tin radical , Silicon radical , thiyl radical
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
