• Title of article

    Selective acylation of 4,5-diamino-9,9′-dimethylxanthene through an aggregation effect

  • Author/Authors

    Muٌiz، نويسنده , , Francisco M. and Simَn، نويسنده , , Luis and Sلez، نويسنده , , Silvia and Raposo، نويسنده , , César and Morلn، نويسنده , , Joaquيn R. and Benedito، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2008
  • Pages
    4
  • From page
    790
  • To page
    793
  • Abstract
    The proximity of the 4,5-diamino groups in a 9,9′-dimethylxanthene skeleton provides unique reactivity due to aggregation effects. While treatment with 1 equiv of an isocyanate yields the diurea and starting material, under similar conditions, Boc2O provides essentially only the monocarbamoyl derivative.
  • Keywords
    Selective acylation , Molecular recognition , Hydrogen-bond catalysis
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2008
  • Journal title
    Tetrahedron Letters
  • Record number

    1860188