Title of article :
Aerobic oxidative iodination of organic molecules activated by sodium nitrite
Author/Authors :
Iskra، نويسنده , , Jernej and Stavber، نويسنده , , Stojan and Zupan، نويسنده , , Marko، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2008
Abstract :
Aerobic oxidative iodination activated by sodium nitrite occurs effectively and selectively with 100% iodine atom economy with air as the oxidant. Silica-supported sulfuric acid was used for the activation of the catalyst and iodination. Thus, I2/NaNO2/air/silica-supported H2SO4 in acetonitrile iodinated aromatics, ketones and aldehydes effectively at ambient temperature.
Keywords :
iodination , Halogenation , Haloperoxidation , Hydrogen peroxide , Organo-halogen compounds , green chemistry , Aerobic halogenation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
