Title of article
Catalytic enantioselective allylation of aldehydes using β-amido functionalized allylstannanes with chiral In(OTf)3/i-Pr-pybox complexes
Author/Authors
Suzuki، نويسنده , , Takamasa and Sengoku، نويسنده , , Tetsuya and Takahashi، نويسنده , , Masaki and Yoda، نويسنده , , Hidemi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
3
From page
4701
To page
4703
Abstract
The enantioselective allylation of aldehydes using a variety of β-amido functionalized allyltributylstannanes proceeded smoothly with good to high yields and enantioselectivities in the presence of 10 mol % of a chiral catalytic complex prepared from In(OTf)3 and 2,6-bis[(S)-4-isopropyloxazolin-2-yl]pyridine {(S)-i-Pr-pybox}, providing the corresponding chiral γ-hydroxy amides.
Keywords
?-Amido allylstannane , aldehyde , ?-Methylene-?-butyrolactone , In(OTf)3 , (S)-i-Pr-pybox , Catalytic enantioselective allylation
Journal title
Tetrahedron Letters
Serial Year
2008
Journal title
Tetrahedron Letters
Record number
1860424
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