Author/Authors :
Kawatsura، نويسنده , , Motoi and Ata، نويسنده , , Fumio and Hirakawa، نويسنده , , Takuya and Hayase، نويسنده , , Shuichi and Itoh، نويسنده , , Toshiyuki، نويسنده ,
Abstract :
The ruthenium-catalyzed highly linear selective allylic amination of monosubstituted allylic acetates with secondary amines was developed. The regioselectivity was controlled by the Ru3(CO)12/2-DPPBA catalyst, and a linear-type aminated product was obtained as a single regioisomer.
Keywords :
Ruthenium , Catalyst , Allylic amination , regioselectivity
