Title of article
Electro- and acid-catalysis in tetrafluoroborate-based ionic liquid: new alternative routes for the oxidation of sulfides with UHP
Author/Authors
Palombi، نويسنده , , Laura and Bocchino، نويسنده , , Carmen and Caruso، نويسنده , , Tonino and Villano، نويسنده , , Rosaria and Scettri، نويسنده , , Arrigo، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
3
From page
5611
To page
5613
Abstract
By means of anodic activation, BF4-based ionic liquid was found to play the triple role of electrolysis/reaction medium, supporting electrolyte and pre-catalyst versus the oxidation of sulfides with UHP. Galvanostatic electrolysis in the presence of substrate and UHP molecules allowed the fast, efficient and selective achievement of sulfoxides. Comparable results have been attained by acid catalysis based on R-CSA.
Keywords
Electrochemical oxidation , Ionic liquid , sulfoxides
Journal title
Tetrahedron Letters
Serial Year
2008
Journal title
Tetrahedron Letters
Record number
1860894
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