Author/Authors :
David John Mycock، نويسنده , , David K. and Sherlock، نويسنده , , Alexandra E. and Glossop، نويسنده , , Paul A. and Hayes، نويسنده , , Christopher J.، نويسنده ,
Abstract :
We have shown that dimethyldioxirane (DMDO) can be used to effect an oxidative partial deprotection of benzylidene acetals derived from both 1,2- and 1,3-diols to afford hydroxy benzoate products. A wide range of functional groups are tolerated, and good to excellent yields are usually observed. The reactions are easy to perform and produce little waste other than acetone.
