Title of article :
A brand-new Pd-mediated generation of benzyne and its [2+2+2] cycloaddition: δ-carbon elimination and concomitant decarboxylation
Author/Authors :
Kim، نويسنده , , Hoo Sook and Gowrisankar، نويسنده , , Saravanan and Kim، نويسنده , , Eun Sun and Kim، نويسنده , , Jae Nyoung، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2008
Abstract :
We found a brand-new method for the generation of aryne from methyl 2-bromobenzoates via the Pd-mediated concomitant δ-carbon elimination and decarboxylation. The generated arynes underwent Pd-mediated [2+2+2] cycloaddition to give triphenylenes.
Keywords :
arynes , PALLADIUM , Decarboxylation , Triphenylene , ?-Carbon elimination
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
