Title of article
Lewis acid-promoted carbonyl addition of 1,3-bis(silyl)propenes
Author/Authors
Tuzina، نويسنده , , Pavel and Somfai، نويسنده , , Peter، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
3
From page
6882
To page
6884
Abstract
A novel synthetic protocol for Lewis acid-promoted addition of 1,3-bis(silyl)propenes to N-phenyl glyoxylamide and ethyl glyoxylate is developed. The reaction does not appear to be influenced by the steric bulk of the 1,3-bis(silyl)propenes, and represents a new approach to vinylation of glyoxylates; the products are obtained in good yields.
Keywords
vinylation , Allylsilane , Ethyl glyoxylate , Tin tetrachloride , 1 , 3]-Brook rearrangement , N-Phenyl glyoxylamide
Journal title
Tetrahedron Letters
Serial Year
2008
Journal title
Tetrahedron Letters
Record number
1861737
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