Title of article
A total synthesis of (+)-isolaurepan
Author/Authors
Tripathi، نويسنده , , Divya Prasanna Kumar، نويسنده , , Pradeep، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
3
From page
7012
To page
7014
Abstract
A versatile and efficient method for the enantioselective synthesis of 2,7-cis-disubstituted oxepane 1c, (+)-isolaurepan, using oxidative resolution of a secondary alcohol and highly diastereoselective Et3SiH/TMSOTf-promoted reductive cyclization of a hydroxy ketone is described.
Keywords
Oxidative resolution of secondary alcohols , Cis-selective cyclization , Cyclic ethers , oxepanes , Isolaurepan
Journal title
Tetrahedron Letters
Serial Year
2008
Journal title
Tetrahedron Letters
Record number
1861819
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