• Title of article

    Rhodium-catalyzed thiophosphinoylation reaction of 1,2-dienes with diphosphine disulfides

  • Author/Authors

    Arisawa، نويسنده , , Mieko and Yamaguchi، نويسنده , , Masahiko، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2009
  • Pages
    3
  • From page
    45
  • To page
    47
  • Abstract
    In the presence of RhH(PPh3)4, the reaction of 1,2-alkadienes, tetramethyldiphosphine disulfide, and camphorsulfonic acid gave (E)-2-dimethylthiophosphinoyl-2-alkenes. The reaction involved the P–P cleavage and the transfer of the thiophosphinoyl group to 1,2-alkadienes with concomitant formation of thiophosphinic anhydride.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2009
  • Journal title
    Tetrahedron Letters
  • Record number

    1862142