Author/Authors :
Vardelle، نويسنده , , Emilie and Martin-Mingot، نويسنده , , Agnès and Jouannetaud، نويسنده , , Marie-Paule and Jacquesy، نويسنده , , Jean-Claude and Marrot، نويسنده , , Jérôme، نويسنده ,
Abstract :
In the superacidic media HF/SbF5, hydroxylation of several Tröger’s bases was performed using sodium persulfate as a hydroperoxonium H3 O 2 + precursor. The obtained products are selectively hydroxylated in good yields on unusual positions of the aromatic rings.
Keywords :
Tr?ger’s bases , Superacid , aromatic amines , Electrophilic aromatic substitution , hydroxylation