Author/Authors :
Bell، نويسنده , , Kelcey and Sadasivam، نويسنده , , Dhandapani V. and Gudipati، نويسنده , , Indra Reddy and Ji، نويسنده , , Hua and Birney، نويسنده , , David، نويسنده ,
Abstract :
Reaction of a toluene solution of 3-oxobutanoyl chloride (14) with Na2CO3 in the presence of a catalytic amount of triethylamine at −78 °C generates a solution of acetylketene (2), the dimer of which was isolated. Acetylketene (2) was trapped with 2-propanone, 2-propanol, and ethyl vinyl ether.