Author/Authors :
Junge، نويسنده , , Henrik and Boddien، نويسنده , , Albert and Capitta، نويسنده , , Francesca and Loges، نويسنده , , Bjِrn and Noyes، نويسنده , , James R. and Gladiali، نويسنده , , Serafino and Beller، نويسنده , , Matthias، نويسنده ,
Abstract :
The ruthenium-catalyzed generation of hydrogen from formic acid was investigated in the presence of amines and halide additives. While amidines and halide additives increase the production of hydrogen with [RuCl2(p-cymene)]2, >330 mL hydrogen/h is generated in the presence of [RuCl2(benzene)]2/dppe and N,N-dimethyl-n-hexylamine.
Keywords :
Ruthenium , Catalysis , Formic acid , Hydrogen
