Author/Authors :
Dalk?l?ç، نويسنده , , Erdin and Güney، نويسنده , , Murat and Da?tan، نويسنده , , Arif and Saracoglu، نويسنده , , Nurullah and Lucchi، نويسنده , , Ottorino De and Fabris، نويسنده , , Fabrizio، نويسنده ,
Abstract :
2-Bromo-3-(trimethylstannyl)cyclopenta-1,3-diene is the key-intermediate for the synthesis of vic-bromo(trimethylstannyl)bicycloolefins via Diels–Alder reaction with dienophiles. The cycloadducts can be cyclotrimerized by copper(I) 2-thiophenecarboxylate (CuTC) to afford functionalized benzocyclotrimers.
Keywords :
cycloaddition , Copper , Diels–Alder , Stereochemistry , Tetrazine , cyclotrimerization
