Title of article :
A preliminary step toward molecular spring driven by cooperative guest binding
Author/Authors :
Ikeda، نويسنده , , Tomohiro and Shinkai، نويسنده , , Seiji and Sada، نويسنده , , Kazuki and Takeuchi، نويسنده , , Masayuki، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2009
Abstract :
A macrocyclic host molecule that comprised two different rotating modules, cerium(IV) bis(porphyrinate)s and ferrocenyl rotating units, exhibiting contraction/expansion motion was synthesized, which can be regarded as a prototype of artificial molecular spring driven by cooperative guest binding in 1:6 stoichiometry.
Keywords :
Molecular recognition , Allosterism , Molecular machinery , Porphyrinoids
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters